NEW YORK, NY Friday Jun.15.2007 / -- Amy Winehouse kicked off MTV's new live music series last week "45th @ Night."

Winehouse performed hits including "Rehab" and "You Know I'm No Good" for the opening of the show, which takes place at MTV's TRL studio.

The British star has already joined up with a two of hip hop's big wigs, Ghostface and Jay-Z. That list is beginning to grow, as Mos Def joined the British singer onstage with The Dap-Kings to perform a new version of her song "Love Is A Losing Game."

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